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Ausgewählte Publikationen

  • B. Wöhrmann, K. P. Lieb, R. Diller, L. Lühmann, J. Keinonen, L. Cleemann and J. Eberth,  The Yrast-Bands in 77Kr and 76Kr. Nuclear Physics A431, 170 (1984) dx.doi.org/10.1016/0375-9474(84)90060-5
  • R. Diller, K. P. Lieb, L. Lühmann, T. Osipowicz, P. Sona, B. Wöhrmann, L. Cleemann and J. Eberth, Decay of Three-Particle High Spin States in 85Y. Z. Physik A - Atoms and Nuclei 321, 659 (1985) dx.doi.org/10.1007/Bf01432443
  • R. Diller, M. Stockburger, D. Oesterhelt and J. Tittor, Resonance Raman Study of the Intermediates of the Halorhodopsin Photocycle. FEBS - Lett. 217, 297 (1987) dx.doi.org/10.1016/0014-5793(87)80682-8
  • R. Diller and M. Stockburger, Kinetic Resonance Raman Studies reveal different Conformational States of Bacteriorhodopsin. Biochemistry 27, 7641 (1988) dx.doi.org/10.1021/bi00420a011
  • G. Schneider, R. Diller and M. Stockburger, Photochemical Quantum Yield of Bacteriorhodopsin from Resonance Raman Scattering as a Probe for Photolysis. Chem. Phys. 131, 17 (1989) dx.doi.org/10.1016/0301-0104(89)87078-8
  • W. Eisfeld, C. Pusch, R. Diller, R. Lohrmann and M. Stockburger, Resonance Raman and Optical Transient Studies on the Light Induced Proton Pump of Bacteriorhodopsin reveal Parallel Photocycles. Biochemistry 32, 7196 (1993) dx.doi.org/10.1021/bi00079a017
  • R. Diller, M. Iannone, R. Bogomolni and R. M. Hochstrasser, Ultrafast Infrared Sectroscopy of Bacteriorhodopsin. Biophys. J. 60, 286 (1991) dx.doi.org/10.1016/S0006-3495(91)82050-1
  • R. M. Hochstrasser, M. A. Pereira, P. A. Share, M. J. Sarisky, Y. R. Kim, S. T. Repinec, R. J. Sension, J. R. G. Thorne,M. Iannone, R. Diller, P. A. Anfinrud, C. Han, T. Lian and B. Locke, Anisotropy Studies of Ultrafast Dipole Reorientation. Proc. Indian Acad. Sci. 103, 351 (1991)
  • M. Iannone, B. R. Cowen, R. Diller, S. Maiti and R. M. Hochstrasser, A High - Repetition - Rate Infrared Pump, Infrared Probe Spectrometer. Appl. Optics 30, 5247 (1992) dx.doi.org/10.1364/AO.30.005247
  • R. Diller, M. Iannone, B. R. Cowen, S. Maiti, R. Bogomolni and R. M. Hochstrasser, Picosecond Dynamics of Bacteriorhodopsin, probed by Time Resolved Infrared Spectroscopy. Biochemistry 31, 5567 (1992) dx.doi.org/10.1021/bi00139a020
  • S. Maiti, B. R. Cowen, R. Diller, M. Iannone, C. C. Moser, P. L. Dutton and R. M. Hochstrasser, Picosecond Infrared Studies of the Photosynthetic Reaction Center. Proc. Natl. Acad. Sci. USA 90, 5247 (1993) dx.doi.org/10.1073/pnas.90.11.5247
  • B. Locke, R. Diller and R. M. Hochstrasser, Ultrafast Infrared Spectroscopy and Protein Dynamics. Review in: Advances in Spectroscopy, Vol 20: Biomolecular Spectroscopy B, (J. H. Clark, R. E. Hester, eds.), J. Wiley and Sons, New York (1993)
  • R. Diller, S. Maiti, G. C. Walker, B. R. Cowen, R. S. Pippenger, R. Bogomolni and R. M. Hochstrasser, Femtosecond Time-Resolved Infrared Laser Study of the J-K Transition of Bacteriorhodopsin. Chem. Phys. Lett. 241, 109 (1995) dx.doi.org/10.1016/0009-2614(95)00598-X
  • R. Dziewior and R. Diller, Femtosecond Infrared Spectroscopy on Bacteriorhodopsin using a Broad Band Carbon Monoxide Laser. Ber. Bunsenges. Phys. Chem. 100, 2103 (1996) dx.doi.org/10.1002/bbpc.19961001231
  • R. Diller, Vibrational Relaxation during the Retinal Isomerization in Bacteriorhodopsin. Chem. Phys. Lett., 295, 47-55 (1998) dx.doi.org/10.1016/S0009-2614(98)00932-4
  • R. Dziewior, K. Romey and R. Diller, Femtosecond Time Resolved Infrared  Spectroscopy of the Ethylenic Stretch Vibration during the all-trans to 13-cis Isomerization of Bacteriorhodopsin. Laser Chem., 19, 173-178 (1999) dx.doi.org/10.1155/1999/97059
  • K. Heyne, U. Alexiev, R. Dziewior and R. Diller, Single and Double Mutants of Bacteriorhodopsin and their Impact on Photoisomerization. Ultrafast Phenomena XI, (T. Elsaesser, J. G. Fujimoto, D. A. Wiersma and W. Zinth, eds.) pp. 681-683  Springer, Berlin (1998)
  • K. Heyne, J. Herbst, B. Dominguez-Herradon, U. Alexiev and R. Diller, Reaction Control in Bacteriorhodopsin: Impact of Arg82 and Asp85 on the Fast Retinal Isomerization, studied in the Second Site Revertant Arg82Ala/Gly231Cys and Various Purple and Blue Forms of Bacteriorhodopsin. J. Phys. Chem. B., 104, 6053-6058 (2000)
  • K. Heyne, J. Herbst, D. Stehlik, B. Esteban, T. Lamparter, J. Hughes and R. Diller, Ultrafast Dynamics of Phytochrome from the Cyanobacterium Synechocystis, reconstituted with Phycocyanobilin and Phycoerythrobilin. Biophys. J. 82, 1004-1016 (2002) dx.doi.org/10.1016/S0006-3495(02)75460-X
  • J. Herbst, K. Heyne and R. Diller, Femtosecond Infrared Spectroscopy of Bacteriorhodopsin Chromophore Isomerization. Science 297, 822-825 (2002) dx.doi.org/10.1126/science.1072144
  • J. Herbst, K. Heyne and R. Diller, Primary Processes in the Photoisomerization of Bacteriorhodopsin studied by Femtosecond Infrared Spectroscopy. Proceedings of the Vth Femtochemistry Conference, Toledo, Spain 2001: Femtochemistry and Femtobiology, (A. Douhal and J. Santamaria, eds.) pp. 764-770 World Scientific (2002)
  • R. Diller, J. Herbst, K. Heyne, M. Ottolenghi, N. Friedman and M. Sheves, Vibrational Dynamics upon photoexcitation of native bacteriorhodopsin (bR) and of the all-trans - locked bR5.12 Ultrafast Phenomena XIII (eds. R. J. D. Miller, M. M. Murnane, N. F. Scherer, A. M. Weiner) pp. 640-642 Springer Series in Chemical Physics, Berlin (2003)
  • I. Y. Chan, F. Peters, J. Herbst, D. Stehlik, B. Esteban, T. Lamparter and R. Diller, Primary Reaction Dynamics of Phytochrome from Agrobacterium tumefaciens. J. Phys. Chem. B, submitted (2005)
  • F. Peters, J. Herbst, J. Tittor, D. Oesterhelt and R. Diller, Primary Reaction Dynamics of Halorhodopsin, observed by sub-Picosecond IR - Vibrational Spectroscopy. Chem. Phys. 323, 109 - 116 (2006) dx.doi.org/10.1016/j.chemphys.2005.08.036
  • R. Diller, R. Jakober, C. Schumann, F. Peters, J. P. Klare and M. Engelhard, Trans-cis Isomerization Reaction Dynamics in Sensory Rhodopsin II by Femtosecond Time-Resolved Mid-IR Spectroscopy: Chromophore and Protein Dynamics. Biopolymers,  82, 358-362 (2006) dx.doi.org/10.1002/bip.20475
  • C. Schumann, R. Groß, N. Michael, T. Lamparter, and R. Diller, Sub-Picosecond Mid-Infrared Spectroscopy of Phytochrome Agp1 from Agrobacterium tumefaciens. ChemPhysChem 8, 1657-1663 (2007) dx.doi.org/10.1002/cphc.200700210
  • R. Groß, C. Schumann, M. Wolf, O. Trentmann, E. Neuhaus, J. P. Klare, M.Engelhard, J. Tittor, R. Diller, Trans-cis reaction dynamics in retinal proteins by sub-ps time-resolved IR spectroscopy: Protein and chromophore dynamics. Proceedings TRVS XIII, (eds. W. Zinth, A. Laubereau), Munich (2007)
  • C. Schumann, R. Groß, N. Michael, R. Diller, T. Lamparter, Sub-picosecond time-resolved infrared spectroscopy of phytochrome. Proceedings TRVS XIII, (eds. W. Zinth, A. Laubereau), Munich (2007)
  • M. Wolf, R. Groß, C. Schumann, T. Domratcheva, B. Person, J. Heberle, R. Diller, Ultrafast Infrared-Spectroscopy on Flavin Systems. Proceedings TRVS XIII, (eds. W. Zinth, A. Laubereau), Munich (2007)
  • C. Schumann, R. Groß, M. M. N. Wolf, N. Michael, T. Lamparter and R. Diller, Sub-Picosecond Mid-Infrared Spectroscopy of the Pfr reaction of Phytochrome Agp1 from Agrobacterium tumefaciens. Biophys. J. 94, 3189-3197 (2008) dx.doi.org/10.1529/biophysj.107.119297
  • M. M. N. Wolf, R. Groß, C. Schumann, J. A. Wolny, V. Schünemann, A. Døssing, H. Paulsen, J. J. McGarvey and R. Diller, Sub-Picosecond Time Resolved Infrared Spectroscopy of High-Spin State Formation in Fe(II) Spin Crossover Complexes. Phys. Chem. Chem. Phys., 10, 4264-4273 (2008) dx.doi.org/10.1039/B802607F
  • M. M. N. Wolf, C. Schumann, R. Groß, T. Domratcheva and R. Diller, Ultrafast Infrared Spectroscopy of Riboflavin: Dynamics, Electronic Structure, and Vibrational Mode Analysis. J. Phys. Chem. B 112, 13424-13432 (2008) dx.doi.org/10.1021/jp804231c
  • R. Groß, C. Schumann, M.N.N. Wolf, J. Herbst, R. Diller, N. Friedman and M. Sheves, Ultrafast Protein Conformational Alterations in Bacteriorhodopsin and its Locked Analogue BR5.12. J. Phys. Chem. B. 113, 7851-7860 (2009) dx.doi.org/10.1021/jp810042f
  • J. A. Wolny, H. Paulsen, J. J. McGarvey,  R. Diller, V. Schünemann and H. Toftlund, Fe(II)  Complexes with the octadentate btpa ligand : A DFT study on a spin crossover system that reveals two distinct high-spin states. Phys. Chem. Chem. Phys. 11, 7562-7575 (2009) dx.doi.org/10.1039/B905328J
  • R. Groß, M. Wolf, C. Schumann, N. Friedman, M. Sheves, L. Li, M. Engelhard, O. Trentmann, H. Neuhaus and R. Diller, Primary Photoinduced Protein Response in Bacteriorhodopsin and Sensory Rhodopsin II. Journal of the American Chemical Society 131, 14868-14878 (2009) dx.doi.org/10.1021/ja904218n
  • M. Colindres Rojas, M. M. N. Wolf, R. Groß, S. Seidel, B. Dietzek, M. Schmitt, J. Popp, G. Hermann and R. Diller, Excited-State Dynamics of Protochlorophyllide Revealed by Sub-picosecond Infrared Spectroscopy. Biophys. J. 100, 260-267 (2011) dx.doi.org/10.1016/j.bpj.2010.11.054
  • M. M. N. Wolf, H. Zimmermann, R. Diller and T. Domratcheva, Vibrational Mode Analysis of Isotope-Labeled Electronically Excited Riboflavin. Journal of Physical Chemistry B, 115, 7621-7628 (2011) http://dx.doi.org/10.1021/jp110784t
  • A. Pasteur, K. Muffler, N. Tippkötter, R. Ulber, C. Meyer, R. Diller,       P. Kampeis, B. König, Entwicklung selektiver Adsorbermaterialien zur Aufarbeitung von beta-Lactamantibiotika, ChemBioTec Review, Vol.3,  6-8 (2011)
  • J. A. Wolny, R. Diller, V. Schünemann, Vibrational spectroscopy on mono- and polynuclear spin-crossover systems, European Journal of Inorganic Chemistry, 2635–2648 (2012) dx.doi.org/10.1002/ejic.201200059
  • S. Rackwitz, J.A. Wolny, K. Muffler, K. Achterhold, R. Rüffer, Y. Garcia, R. Diller and V. Schünemann, Vibrational properties of the polymeric spin crossover (SCO) Fe(II) complexes [{Fe(4-amino-1,2,4-triazole)3 }2 ]n : A nuclear inelastic scattering (NIS), Raman and DFT study, Phys. Chem. Chem. Phys. 14, 14650-14660 (2012) dx.doi.org/10.1039/C2CP41455D
  • K. Chevalier, M. M. N. Wolf, A. Funk, M. Andres, M. Gerhards and R. Diller, Transient IR spectroscopy and ab-initio calculations on ESIPT 3-hydroxyflavone solvated in acetonitrile, Phys. Chem. Chem. Phys. 14, 15007-15020 (2012) dx.doi.org/10.1039/c2cp41077j
  • W. Jin, F. Rupp, K. Chevalier, M.M.N. Wolf, M. Colindres Rojas, G. Lefkidis, H.-J. Krüger, R. Diller and W. Hübner, Combined theoretical and experimental study of spin and charge dynamics on the homodinuclear complex [Ni2II(L-N4Me2)(emb)], Phys. Rev. Lett. 109, 267209 (2012) dx.doi.org/10.1103/PhysRevLett.109.267209
  • F. Rupp, K. Chevalier, M. M. N. Wolf, H.-J. Krüger, C. v. Wüllen, Y. Nosenko, G. Niedner-Schatteburg, C. Riehn and R. Diller, Photoinduced Processes in Cobalt-Complexes: Condensed Phase and Gas Phase, Proceed. Int. Conference on Ultrafast Phenomena XVIII (2013) dx.doi.org/10.1051/epjconf/20134105045
  • B. Zienicke, I. Molina, R. Glenz, P. Singer, D. Ehmer, F. Velazquez Escobar, P. Hildebrandt, R. Diller and T. Lamparter, Unusual spectral properties of bacteriophytochrome Agp2 result from a deprotonation of the chromophore in the red-absorbing form Pr, J. Biol. Chem. 288, 31738-31751 (2013) dx.doi.org/10.1074/jbc.M113.479535
  • Katharina Chevalier, Anneken Grün, Anke Stamm, Yvonne Schmitt, Markus Gerhards, Rolf Diller, ESIPT and Photodissociation of 3 Hydroxychromone in Solution: Photoinduced Processes Studied by Static and Time Resolved UV/Vis, Fluorescence and IR Spectroscopy, J. Phys. Chem. A 117, 11233-11245 (2013) http://dx.doi.org/10.1021/jp407252y
  • Y. Schmitt, K. Chevalier, F. Rupp, M. Becherer, A. Grün, F. Walz, A. Rijs, F. Breher, R. Diller, M. Gerhards, W. Klopper, In-depth exploration of the photophysics of a trinuclear palladium complex, Phys. Chem. Chem. Phys. 16, 832-8338 (2014)  http://dx.doi.org/10.1039/C4CP00175C
  • D. Imanbaew, Y. Nosenko, C. Kerner, K. Chevalier, F. Rupp, C. Riehn, W.R. Thiel, R. Diller, Excited state dynamics of a Ruthenium(II)-catalyst studied by transient photofragmentation in the gas phase and transient absorption in solution, Chem. Phys. 442, 53-61 (2014) http://dx.doi.org/10.1016/j.chemphys.2014.03.005
  • P. Singer, S. Fey, A.H. Göller, G. Hermann, R. Diller, Femtosecond Dynamics in the Lactim Tautomer of Phycocyanobilin: A Long-Wavelength Absorbing Model Compound for the Phytochrome Chromophore, Chem. Phys. Chem. 15, 3824-3831 (2014)http://dx.doi.org/10.1002/cphc201402383
  • D. Imanbaew, Y. Nosenko, K. Chevalier, F. Rupp, C. Kerner, F. Breher, W.R. Thiel, R. Diller, C. Riehn, Excited-state dynamics of catalytically active transition metal complexes studied by transient photofragmentation in gas phase and transient absorption in solution, Proceedings of the XIXth Conference on Ultrafast Phenomena 2014 http://dx.doi.org/10.1364/UP.2014.08.Tue.P2.28
  • M. Zimmer, F. Rupp, P. Singer, F. Walz, F. Breher, W. Klopper, R. Diller, M. Gerhards, Time-Resolved IR Spectroscopy of a Trinuclear Palladium Complex in Solution, Phys. Chem. Chem. Phys. 17, 14138(2015) http://dx.doi.org/10.1039/c5cp00959f
  • C. Carreira-Blanco, P. Singer, R. Diller, J.L. Pérez-Lustres, Ultrafast Deactivation of Bilirubin: Dark Intermediates and Two-Photon Isomerization, Phys. Chem. Chem. Phys. 18, 7148-7155 (2016) http://dx.doi.org/10.1039/C5CP06971H
  • P. Singer, S. Wörner, T. Lamparter, R. Diller, Spectroscopic investigation on the primary photoreaction of bathy phytochrome Agp2-Pr of Agrobacterium fabrum: Isomerization in a pH dependent H-bond network, Chem. Phys. Chem. 17, 1288-1297 (2016) http://dx.doi.org/10.1002/cphc.201600199
  • F. Rupp, K. Chevalier, M. Graf, M. Schmitz, H. Kelm A. Grün, M. Zimmer, M. Gerhards, C. van Wüllen, H.-J. Krüger, R. Diller, Spectroscopic, Structural, and Kinetic Investigation of the Ultrafast Spin Crossover in a Unusual Cobalt(II) Semiquinonate Radical Complex, Chemistry - A European Journal 23, 2119-2132 (2017)  http://dx.doi.org/10.1002/chem.201604546
  • B. Schäfer, T. Bauer, I. Faus, J. Wolny, F. Dahms, O. Fuhr, S. Lebedkin, H.-C. Wille, K. Schlage, K. Chevalier, F. Rupp, R. Diller, V. Schünemann, M. Kappes, M. Ruben, A Luminescent Pt2Fe Spin Crossover Complex, Dalton Transactions 46, 2289-2302 (2017) http://dx.doi.org/10.1039/C6DT04360G
  • K. Schwing, C. Riehn, R. Diller, G. Nieder-Schatteburg, M. Gerhards, Physical Chemistry for Life Sciences, Bunsenmagazin 2, 37-40 (2017)
  • S.V. Kruppa, F. Bäppler, W. Klopper, S.P. Walg, W.R. Thiel, R. Diller, C. Riehn, Ultrafast excited-state relaxation of a binuclear Ag(I) phosphine complex in gas Phase and solution, PCCP, 1-27 (2017) http://dx.doi.org/10.1039/C7CP04128D















  • R. Diller, Primary Reactions in Retinal Proteins, in: Ultrashort Laser Pulses in Biology and Medicine (M. Braun, P. Gilch, W. Zinth, eds.), ca. 30 pages, Springer Berlin ISBN-13: 978-3540735656  (2008) 
  • R. Diller, IR Spectroscopy of Protein Dynamics: Ultrafast Kinetics, in: Encyclopedia of Biophysics (ed.: Gordon C. Roberts), Springer, ISBN-0: 364216711X (2012)